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31.
32.
堇青石的矿物学特性及其应用   总被引:1,自引:0,他引:1  
堇青石作为一种天然矿物已被研究多年,它广泛分布于岩浆岩、变质岩和伟晶岩中,但确很少富集成矿。基于堇青石所具有的许多优良性能,使它在耐火材料、精细陶瓷、计算机集成电路的基片等领域中得到了广泛的应用。本文将从堇青石的矿物学角度出发,阐述人工合成堇青石的研究现状及发展前景。  相似文献   
33.
The Betic–Rif belt, in the western Mediterranean, experienced a pre-Alpine history and was later extensively reworked by major Alpine tectonics. There is abundant data showing that the Betic chain suffered very high cooling rates during its Alpine history, constrained mainly by geochronology using various isotopic systems and by palaeontological age determinations. In the westernmost part of the chain the high closure-temperature isotopic systems recorded Miocene high-grade metamorphism in the country rocks. In order to constrain the later stages of cooling, fission-track analysis has been applied to both zircon and apatite. The results point to extremely high rates of cooling (400 °C/Ma) between 21 and 19 Ma. Rates slowed to 100 °C/Ma for the time period 19 to about 12 Ma. The fission-track analysis also confirms the existence of an extensional tectonic stage between 19 and 17 Ma.  相似文献   
34.
Mantle peridotites from the Erro–Tobbio (ET) ophioliticunit (Voltri Massif, Ligurian Alps) record a tectono-metamorphicdecompressional evolution, indicated by re-equilibration fromspinel- to plagioclase- to amphibole-facies conditions, andprogressive deformation from granular to tectonite to mylonitefabrics. The peridotites are considered to represent subcontinentallithospheric mantle that was tectonically denuded during riftingand opening of the Jurassic Ligurian Tethys ocean, similar tothe Northern Apennine (External Ligurides) ophiolitic peridotites.We performed chemical and isotopic investigations on selectedgranular and tectonite spinel peridotites and plagioclase tectonitesand mylonites, with the aim of defining the nature of the mantleprotoliths, and to date the onset of exhumation of the ET peridotites.Spinel- and plagioclase-bearing tectonites and mylonites exhibitheterogeneous bulk-rock major and trace element composition,despite rather homogeneous mineral chemistry, thus indicatingthat the ET mantle protoliths record a composite history ofpartial melting and melt migration by reactive porous flow.The lack of correlation between the observed geochemical heterogeneityand the structural type (granular, tectonite, mylonite) indicatesthat the inferred reactive porous flow event preceded the exhumation-relatedlithospheric history of the Erro–Tobbio mantle. The tectono-metamorphicevolution caused systematic chemical changes in minerals: (1)Al decrease in orthopyroxene; (2) Al decrease, and Cr and Tiincrease in spinels; (3) Al and Sr decrease, Cr, Ti, Zr, Sc,V and middle to heavy rare earth element increase and developmentof a negative Eu anomaly in clinopyroxene. The studied sampleshave Nd isotope compositions consistent with a mid-ocean ridgebasalt mantle reservoir. Sm/Nd isotope data on plagioclase andclinopyroxene separates (and corresponding whole rocks) fromtwo plagioclase peridotites, representative of the plagioclase-bearingmylonitic extensional shear zone, have yielded ages of 273 ±16 Ma and 313 ± 16 Ma, for the plagioclase-facies recrystallizationstage, significantly older than the expected Jurassic age. Thisindicates that the Erro–Tobbio peridotites represent subcontinentallithospheric mantle that was tectonically exhumed from spinel-faciesdepths to shallower lithospheric levels during Late Carboniferous–Permiantimes. Our results are consistent with the previously documentedevidence for an extensional regime in the Europe–Adrialithosphere during Late Palaeozoic time, and they representthe first record that extensional mechanisms were also activeat lithospheric mantle levels. KEY WORDS: plagioclase-bearing peridotites; subcontinental lithospheric mantle; mantle exhumation; Sm/Nd dating  相似文献   
35.
镁质粘土在碱性耐火材料工业应用的初步探索   总被引:1,自引:0,他引:1  
章人骏 《地球学报》1998,19(1):77-83
本研究项目的主要步骤是把镁质粘土和橄榄岩或焦油镁砂砖废料在箱式电炉里进行烧结试验(温度1200~1250℃)。同时测定了原料、烧结样品和5种产品的物理性质和矿物组分。结果表明,产品里的矿物多是富镁的高熔点矿物,包括继承性的或新生的镁橄榄石和方镁石,少量钙镁橄榄石、镁黄长石以及痕量硅酸二钙。2号产品含较多的斜顽辉石,由滑石或海泡石转化而成,它的熔点较低。试验表明,妥善选择原料和配方是走向成功的第一步,而瘠性和塑性材料相配合,则是传统经验的重现。在这种场合,镁质粘土作为结合粘土,起了很大作用。利用氧气煤气火焰快速测定熔点也是有意义的尝试。  相似文献   
36.
X射线荧光光谱法在耐火材料成分分析中的应用   总被引:4,自引:1,他引:4       下载免费PDF全文
李国会  徐国令  李晓莉 《岩矿测试》2003,22(3):217-220224
采用熔融法制样,用X射线荧光光谱法对耐火材料中的Na2O、MgO、Al2O3、SiO2、K2O、CaO、TiO2、Cr2O3、MnO、Fe2O3、ZrO2、HfO2组分进行测定,使用康普顿散射线作内标和经验系数法校正基体效应,经标准物质检验与标准值吻合,大部分组分的RSD<5%(n=10)。  相似文献   
37.
对广西凭祥叫弄英安岩风化剖面中6个难熔元素的活动性进行了研究。结果表明,Ti,Nb和Ta 3种元素在整个风化成土过程中基本上保持了它们的不活动性。Zr,Hf和Th在风化的初期阶段基本上保持不活动,而在风化中期表现出一定的富集,风化高级阶段则有明显的富集。Th的富集可能与风化壳表层(已剥蚀)淋溶出来的Th向下迁移过程中被氧化铁吸附和形成磷酸盐矿物有关,而Zr的富集则可能与淋溶出来的Zr与SiO2或磷酸盐结合形成某种硅酸盐矿物和磷酸盐矿物有关,具体富集原因还需作进一步的研究。  相似文献   
38.
大洋橄榄岩和洋中脊玄武岩是地幔熔融和熔体萃取过程中的互补产物 ,地幔熔融和熔体萃取过程形成洋壳 ,因此大洋橄榄岩和洋中脊玄武岩的研究可提供这一过程的独立信息。通过大洋橄榄岩和洋中脊玄武岩的岩石学与地球化学研究 ,特别是痕量元素在熔融和熔体演化过程中地球化学行为的研究 ,对定量描述洋中脊下地幔熔融动力学和认识化学地球动力学模式是十分重要的。目前 ,大洋橄榄岩的研究 ,已成为岩石学研究的前沿领域之一。  相似文献   
39.
In Liaoning, Hunan, Guangxi, Guizhou, Gansu, Sichuan, Anhui, Jilin and other provinces in China, there is a wide occurrence of metal quantity over 1000 tons of refractory gold ores, principally because of low gold recoveries and become "stay mine". Features of refi'actory gold ores are: gold in micro-particles or a microscopic state that is wrapped in pyrite, presence of arsenopyrite and other sulfide minerals or disseminated in the crystal lattice of sulfide minerals; harmful impurity elements such as arsenic, carbon, mercury, antimony, copper with high content are closely related with the gold, and these elements affect the contact reaction between the gold and solvent extraction, making the recovery of the gold extraction process low. In the past 20 years, overseas countries have developed the application of the roasting oxidation method, hot acid (alkali) oxidation, bacterial oxidation and flash chlorination oxidation technology to solve this problem.Among these, biological oxidation has developed rapidly in the domestic market and gold enterprises abroad because of its low investment in infrastructure, low production costs, less environmental pollution, simple process and easy control, etc.  相似文献   
40.
Os isotope ratios of mantle peridotites have been considered to be largely immune to recent melt-rock interaction. However, Os isotope ratios and PGE (Platinum group elements) concentrations of the Yong’an xenoliths have been significantly modified by melt percolation, and are not suitable for determining the formation age of lithosphere mantle in Yong’an. In this study, the Yong’an spinel peridotite xenoliths are divided into two groups: N-Type and E-Type. The N-Type group including cpx (clinopyroxene)-poor lherzolite and harzburgite, shows a large variation of Cr#(sp) (13.2-48) and sulfur contents (from 171 ppm to below detection limit), whereas the E-Type peridotites are mainly refractory harzburgites and are characterized by high Cr#(sp) (35.3-42.2) and overall low sulfur contents (below 51 ppm). Both types show similar major and REE (rare earth element) patterns. Furthermore, the N-Type peridotites display a restricted range of iridium-group PGE (IPGE), Os/Ir and Ru/Ir ratios (Os/Ir = 0.64-1.12, Ru/Ir = 1.52-1.79) and variable palladium-group PGE (PPGE) contents (3.4-14.9 ppb), whereas the E-Type peridotites show a large variation of Os/Ir and Ru/Ir ratios (Os/Ir = 0.33-0.84, Ru/Ir = 0.94-1.6), and a restricted range of PPGE (4.3-6.9 ppb). 187Os/188Os ratios of E-Type peridotites are higher than those of N-Type peridotites at comparable fertility levels. These results suggest that N-Type peridotites may have been overprinted by metasomatism via small melt fractions, in which the percolation of the volatile-rich, small melt fractions only resulted in LILE (large ion lithophile element) enrichment of clinopyroxene, and their whole rock PGE contents and Re-Os isotope values were little changed. Moreover, E-Type peridotites may have been modified by melt-rock reaction involving relatively large melt fractions, which may result in the formation of secondary cpx and olivine and the removal of IPGE-bearing minerals such as Ru-Os-(Ir) alloys or laurite, followed by precipitation of secondary sulfides from melt with radiogenic isotopic signature.  相似文献   
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